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Date of peer-review: October 1994
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TYPES OF HAZARD / EXPOSURE | ACUTE HAZARDS / SYMPTOMS | PREVENTION | FIRST AID / FIRE FIGHTING |
FIRE | Extremely
flammable. |
NO open
flames, NO sparks, and NO smoking. |
Shut off
supply; if not possible and no risk to surroundings, let the fire burn
itself out; in other cases extinguish with carbon dioxide, water spray,
powder. |
EXPLOSION | Gas/air
mixtures are explosive. |
Closed
system, ventilation, explosion-proof electrical equipment and lighting.
Use non-sparking handtools. |
In case of
fire: keep cylinder cool by spraying with water. Combat fire from a
sheltered position. |
EXPOSURE | AVOID
EXPOSURE OF (PREGNANT) WOMEN! |
IN ALL
CASES CONSULT A DOCTOR! | |
Inhalation | Confusion.
Dizziness. Headache. Nausea. Unconsciousness. Weakness. |
Ventilation,
local exhaust, or breathing protection. |
Fresh air,
rest. Artificial respiration if indicated. Refer for medical attention.
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Skin | |||
Eyes | |||
Ingestion |
SPILLAGE DISPOSAL | PACKAGING & LABELLING | |||||||
Evacuate
danger area! Consult an expert! Ventilation. (Extra personal protection:
self-contained breathing apparatus). |
EU
Classification Symbol: F+, T R: 61-12-23-48/23 S: 53-45 Note: E UN Classification UN Hazard Class: 2.3 UN Subsidiary Risks: 2.1 | |||||||
EMERGENCY RESPONSE | STORAGE | |||||||
Transport
Emergency Card: TEC (R)-827 NFPA Code: H3; F4; R0 |
Fireproof.
Cool. | |||||||
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IMPORTANT DATA | |||
PHYSICAL
STATE; APPEARANCE: ODOURLESS, TASTELESS, COLOURLESS COMPRESSED GAS. PHYSICAL DANGERS: The gas mixes well with air, explosive mixtures are easily formed. The gas penetrates easily through walls and ceilings. CHEMICAL DANGERS: In the presence of finely dispersed metal powders the substance forms toxic and flammable carbonyls. May react vigorously with oxygen, acetylene, chlorine, fluorine, nitrous oxide. OCCUPATIONAL EXPOSURE LIMITS: TLV: 25 ppm; 29 mg/m^3 (as TWA) (ACGIH 1994-1995). MAK: 30 ppm; 33 mg/m^3; Pregnancy: B (harmful effect probable in spite of observance of MAK) (1993). |
ROUTES OF
EXPOSURE: The substance can be absorbed into the body by inhalation. INHALATION RISK: A harmful concentration of this gas in the air will be reached very quickly on loss of containment. EFFECTS OF SHORT-TERM EXPOSURE: The substance may cause effects on the blood, cardiovascular system and central nervous system. Exposure at high levels may result in lowering of consciousness and death. Medical observation is indicated. EFFECTS OF LONG-TERM OR REPEATED EXPOSURE: The substance may have effects on the nervous system and the cardiovascular system, resulting in neurological and cardiac disorders. Suspected to cause reproductive effects such as neurological problems, low birth weight, increased still births, and congenital heart problems. | ||
PHYSICAL PROPERTIES | |||
Boiling
point: -191°C Melting point: -205°C Solubility in water, ml/100 ml at 20°C: 2.3 Relative vapour density (air = 1): 0.97 |
Flash point:
Flammable Gas Auto-ignition temperature: 605°C Explosive limits, vol% in air: 12.5-74.2 | ||
ENVIRONMENTAL DATA | |||
NOTES | |||
Carbon monoxide is a product of incomplete combustion of coal, oil,
wood. It is present in vehicle exhaust and tobacco smoke. Depending on the
degree of exposure, periodic medical examination is indicated. No odour
warning if toxic concentrations are present. | |||
ADDITIONAL INFORMATION | |||
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© IPCS, CEC 2001 |
See Also: Toxicological Abbreviations Carbon monoxide (EHC 13, 1979, 1st edition) Carbon monoxide (EHC 213, 1999, 2nd edition)