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Date of peer-review: November 1998
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TYPES OF HAZARD / EXPOSURE | ACUTE HAZARDS / SYMPTOMS | PREVENTION | FIRST AID / FIRE FIGHTING |
FIRE | Combustible.
Liquid formulations containing organic solvents may be flammable.
|
NO open
flames. |
Powder,
AFFF, foam, carbon dioxide. |
EXPLOSION |
EXPOSURE | PREVENT
DISPERSION OF DUST! STRICT HYGIENE! AVOID EXPOSURE OF ADOLESCENTS AND
CHILDREN! |
IN ALL
CASES CONSULT A DOCTOR! | |
Inhalation | Abdominal
cramps. Convulsions. Dizziness. Sweating. Nausea. Unconsciousness.
Pupillary constriction, muscle cramp, excessive salivation. Symptoms may
be delayed (see Notes). |
Local
exhaust or breathing protection. |
Fresh air,
rest. Artificial respiration if indicated. Refer for medical attention.
|
Skin | MAY BE
ABSORBED! (See Inhalation). |
Protective
gloves. Protective clothing. |
Remove
contaminated clothes. Rinse and then wash skin with water and soap. Refer
for medical attention. |
Eyes | (Further see
inhalation.) |
Face shield,
or eye protection in combination with breathing protection. |
First rinse
with plenty of water for several minutes (remove contact lenses if easily
possible), then take to a doctor. |
Ingestion | (See
Inhalation). |
Do not eat,
drink, or smoke during work. Wash hands before eating. |
Rinse mouth.
Give a slurry of activated charcoal in water to drink. Induce vomiting
(ONLY IN CONSCIOUS PERSONS!). Refer for medical attention.
|
SPILLAGE DISPOSAL | PACKAGING & LABELLING | |||||||
Do NOT wash
away into sewer. Sweep spilled substance into containers; if appropriate,
moisten first to prevent dusting. Carefully collect remainder, then remove
to safe place. Chemical protection suit including self-contained breathing
apparatus. |
Do not
transport with food and feedstuffs. Marine pollutant. EU Classification Symbol: T+ R: 24-28 S: (1/2-)23-28-36/37-45 UN Classification UN Hazard Class: 6.1 UN Pack Group: I | |||||||
EMERGENCY RESPONSE | STORAGE | |||||||
Transport
Emergency Card: TEC (R)-61G41a |
Provision to
contain effluent from fire extinguishing. Separated from food and
feedstuffs. Well closed. | |||||||
|
|
IMPORTANT DATA | |||
PHYSICAL
STATE; APPEARANCE: COLOURLESS CRYSTALS, WITH CHARACTERISTIC ODOUR. CHEMICAL DANGERS: On combustion, forms toxic and corrosive gases. OCCUPATIONAL EXPOSURE LIMITS: TLV: 0.1 mg/m^3 (as TWA) (skin) (A4) (ACGIH 1998). |
ROUTES OF
EXPOSURE: The substance can be absorbed into the body by inhalation and through the skin and by ingestion. INHALATION RISK: Evaporation at 20°C is negligible; a harmful concentration of airborne particles can, however, be reached quickly on spraying or when dispersed, especially if powdered. EFFECTS OF SHORT-TERM EXPOSURE: The substance may cause effects on the nervous system, resulting in convulsions and respiratory failure. Cholinesterase inhibitor. Exposure may result in death. The effects may be delayed. Medical observation is indicated. | ||
PHYSICAL PROPERTIES | |||
Melting
point: 49.2°C Density: 1.15 Solubility in water, g/100 ml: 0.03 Vapour pressure, Pa at 30°C: <1 |
Octanol/water partition coefficient as log Pow:
3.3 | ||
ENVIRONMENTAL DATA | |||
The substance is very toxic to aquatic organisms. Avoid release to
the environment in circumstances different to normal use.
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NOTES | |||
Depending on the degree of exposure, periodic medical examination
is indicated. Specific treatment is necessary in case of poisoning with
this substance; the appropriate means with instructions must be available.
If the substance is formulated with solvent(s) also consult the card(s)
(ICSC) of the solvent(s). Carrier solvents used in commercial formulations
may change physical and toxicological properties. Do NOT take working
clothes home. Bayer 68138, Bay SRA 3886, ENT 27572, Nemacur, Nemacur P,
and NSC 195106 are trade names. | |||
ADDITIONAL INFORMATION | |||
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© IPCS, CEC 2001 |
See Also: Toxicological Abbreviations Fenamiphos (PDS) Fenamiphos (WHO Pesticide Residues Series 4) Fenamiphos (Pesticide residues in food: 1977 evaluations) Fenamiphos (Pesticide residues in food: 1978 evaluations) Fenamiphos (Pesticide residues in food: 1980 evaluations) Fenamiphos (Pesticide residues in food: 1985 evaluations Part II Toxicology) Fenamiphos (Pesticide residues in food: 1987 evaluations Part II Toxicology) Fenamiphos (Pesticide residues in food: 1997 evaluations Part II Toxicological & Environmental) Fenamiphos (JMPR Evaluations 2002 Part II Toxicological)