International Chemical Safety Cards

1,2,3-TRICHLOROPROPANE ICSC: 0683

1,2,3-TRICHLOROPROPANE
Glycerol trichlorohydrin
Allyl trichloride
Trichlorohydrin
C3H5Cl3 / CH2ClCHClCH2Cl
Molecular mass: 147.4
CAS # 96-18-4
RTECS # TZ9275000
ICSC # 0683
UN # 2810
EC # 602-062-00-X
TYPES OF
HAZARD/
EXPOSURE 		ACUTE HAZARDS/
SYMPTOMS 		PREVENTION FIRST AID/
FIRE FIGHTING
FIRE Combustible. Gives off irritating or toxic fumes (or gases) in a fire.
NO open flames.
Powder, alcohol-resistant foam, water spray, carbon dioxide.
EXPLOSION Above 74°C explosive vapour/air mixtures may be formed. Risk of fire and explosion on contact with strong oxidants, strong bases and metals.
Above 74°C use a closed system, ventilation, and explosion-proof electrical equipment.
In case of fire: keep drums, etc., cool by spraying with water.
EXPOSURE


  • INHALATION
    		• Cough. Drowsiness. Headache. Sore throat. Unconsciousness.
    		Ventilation, local exhaust, or breathing protection.
    		Fresh air, rest. Artificial respiration if indicated. Refer for medical attention.
  • SKIN
    		• MAY BE ABSORBED! Dry skin. Redness. Prickling.
    		Protective gloves. Protective clothing.
    		Remove contaminated clothes. Rinse skin with plenty of water or shower. Refer for medical attention.
  • EYES
    		• Redness. Pain.
    		Safety spectacles, face shield.
    		First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then take to a doctor.
  • INGESTION
    		• Drowsiness. Headache. Unconsciousness.
    		Do not eat, drink, or smoke during work. Wash hands before eating.
    		Rinse mouth. Do NOT induce vomiting. Refer for medical attention.
    SPILLAGE DISPOSAL STORAGE PACKAGING & LABELLING
    Collect leaking and spilled liquid in sealable containers as far as possible. Absorb remaining liquid in sand or inert absorbent and remove to safe place. Do NOT let this chemical enter the environment (extra personal protection: filter respirator for organic gases and vapours).
    		Separated from strong oxidants, strong bases, metals. Cool. Keep in a well-ventilated room.

    Xn symbol
    R: 20/21/22
    S: (2-)37/39
    Note: D
    UN Hazard Class: 6.1
    UN Packing Group: III
    Severe marine pollutant.
    SEE IMPORTANT INFORMATION ON BACK
    ICSC: 0683 Prepared in the context of cooperation between the International Programme on Chemical Safety & the Commission of the European Communities © IPCS CEC 1993 No modifications to the International version have been made except to add the OSHA PELs, NIOSH RELs and IDLH values.

    International Chemical Safety Cards

    1,2,3-TRICHLOROPROPANE ICSC: 0683

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    PHYSICAL STATE; APPEARANCE:
     COLOURLESS LIQUID , WITH CHARACTERISTIC ODOUR.

    PHYSICAL DANGERS:
     The vapour is heavier than air.

    CHEMICAL DANGERS:
     The substance decomposes on burning producing toxic fumes of chlorine (see ICSC 0126) and phosgene (see ICSC 0007). Reacts violently with metals causing explosion hazard.

    OCCUPATIONAL EXPOSURE LIMITS (OELs):
     TLV: 10 ppm ; 60 mg/m3 (as TWA) (skin) A3 (Animal Carcinogen) (ACGIH 1997).
    OSHA PEL: TWA 50 ppm (300 mg/m3)
    NIOSH REL: Ca TWA 10 ppm (60 mg/m3) skin See Appendix A
    NIOSH IDLH: Potential occupational carcinogen 100 ppm


    		ROUTES OF EXPOSURE:
     The substance can be absorbed into the body by inhalation of its vapour ,through the skin and by ingestion.

    INHALATION RISK:
     A harmful contamination of the air will be reached rather slowly on evaporation of this substance at 20°C.

    EFFECTS OF SHORT-TERM EXPOSURE:
     The substance irritates the eyes, the skin and the respiratory tract. The substance may cause effects on the liver , resulting in liver damage. Exposure at high concentrations may result in unconsciousness.

    EFFECTS OF LONG-TERM OR REPEATED EXPOSURE:
     This substance is probably carcinogenic to humans.
    PHYSICAL
    PROPERTIES
    Boiling point: 156°C
    Melting point: -14°C
    Relative density (water = 1): 1.4
    Solubility in water: none
    Vapour pressure, kPa at 20°C: 0.29
    Relative vapour density (air = 1): 5.1
    		 Relative density of the vapour/air-mixture at 20°C (air = 1): 1.01
    Flash point: 74°C
    Auto-ignition temperature: 304°C
    Explosive limits, vol% in air: 3.2-12.6
    Octanol/water partition coefficient as log Pow: 2.27
    ENVIRONMENTAL
    DATA
         		The substance is harmful to aquatic organisms. This substance may be hazardous to the environment; special attention should be given to fish.
    N O T E S
    Transport Emergency Card: TEC (R)-61G61c
    NFPA Code: H3; F2; R0;
    ADDITIONAL INFORMATION


    ICSC: 0683 1,2,3-TRICHLOROPROPANE
    © IPCS, CEC, 1993
    IMPORTANT LEGAL NOTICE: Neither NIOSH, the CEC or the IPCS nor any person acting on behalf of NIOSH, the CEC or the IPCS is responsible for the use which might be made of this information. This card contains the collective views of the IPCS Peer Review Committee and may not reflect in all cases all the detailed requirements included in national legislation on the subject. The user should verify compliance of the cards with the relevant legislation in the country of use. The only modifications made to produce the U.S. version is inclusion of the OSHA PELs, NIOSH RELs and IDLH values.