International Chemical Safety Cards
AZINPHOS-METHYL
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ICSC: 0826
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AZINPHOS-METHYL
Phosphorodithioic acid O,O-dimethyl S-((4-oxo-11,2,3-benzotriazin-3-(4H)-yl)methyl) ester
S-3,4-Dihydro-4-oxo-1,2,3-benzotriazin-3-ylmethyl) O,O-dimethyl phosphorodithioate
C10H12N3O3PS2
Molecular mass: 317.3
CAS # 86-50-0
RTECS # TE1925000
ICSC # 0826
UN # 2783
EC # 015-039-00-9
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TYPES OF HAZARD/ EXPOSURE
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ACUTE HAZARDS/ SYMPTOMS
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PREVENTION
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FIRST AID/ FIRE FIGHTING
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FIRE
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Combustible.
Liquid formulations containing organic solvents may be flammable.
Gives off irritating or toxic fumes (or gases) in a fire.
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NO open flames.
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Powder, water spray, foam, carbon dioxide.
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EXPLOSION
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EXPOSURE
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PREVENT DISPERSION OF DUST!
STRICT HYGIENE!
AVOID EXPOSURE OF ADOLESCENTS AND CHILDREN!
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IN ALL CASES CONSULT A DOCTOR!
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INHALATION
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Headache.
Pupillary constriction, muscle cramp, excessive salivation.
Sweating.
Nausea.
Dizziness.
Wheezing.
Laboured breathing.
Convulsions.
Unconsciousness.
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Ventilation (not if powder), local exhaust, or breathing protection.
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Fresh air, rest.
Artificial respiration if indicated.
Refer for medical attention.
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SKIN
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MAY BE ABSORBED!
(see Inhalation).
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Protective gloves.
Protective clothing.
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Remove contaminated clothes.
Rinse and then wash skin with water and soap.
Refer for medical attention.
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EYES
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Blurred vision.
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Face shield,
or eye protection in combination with breathing protection if powder.
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First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then take to a doctor.
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INGESTION
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Abdominal cramps.
Vomiting.
Diarrhoea.
Blurred vision
(further see Inhalation).
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Do not eat, drink, or smoke during work.
Wash hands before eating.
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Induce vomiting (ONLY IN CONSCIOUS PERSONS!).
Refer for medical attention.
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SPILLAGE DISPOSAL
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STORAGE
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PACKAGING & LABELLING
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Do NOT wash away into sewer.
Sweep spilled substance into sealable containers; if appropriate, moisten first to prevent dusting.
Carefully collect remainder,
then remove to safe place
(extra personal protection: complete protective clothing including self-contained breathing apparatus).
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Separated from
food and feedstuffs.
Well closed.
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Do not transport with food and feedstuffs.
T+ symbol
R: 24-28
S: (1/2-)28-36/37-45
UN Hazard Class: 6.1
UN Packing Group: II
Severe marine pollutant.
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SEE IMPORTANT INFORMATION ON BACK
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ICSC: 0826
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Prepared in the context of cooperation between the International Programme on Chemical Safety & the Commission of the European Communities © IPCS CEC 1993
No modifications to the International version have been made except to add the OSHA PELs, NIOSH RELs and IDLH values.
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