International Chemical Safety Cards

CYCLOHEXANETHIOL ICSC: 0032

CYCLOHEXANETHIOL
Cyclohexyl mercaptan
C6H11SH
Molecular mass: 116.2
CAS # 1569-69-3
RTECS # GV7525000
ICSC # 0032
UN # 3054
TYPES OF
HAZARD/
EXPOSURE 		ACUTE HAZARDS/
SYMPTOMS 		PREVENTION FIRST AID/
FIRE FIGHTING
FIRE Flammable.
NO open flames, NO sparks, and NO smoking.
Powder, AFFF, foam, carbon dioxide.
EXPLOSION Above 43°C explosive vapour/air mixtures may be formed.
Above 43°C use a closed system, ventilation, and explosion-proof electrical equipment.
In case of fire: keep drums, etc., cool by spraying with water.
EXPOSURE


  • INHALATION
    		• Cough. Dizziness. Headache. Nausea. Unconsciousness. Vomiting. Weakness.
    		Ventilation, local exhaust, or breathing protection.
    		Fresh air, rest. Refer for medical attention.
  • SKIN
    		• Redness.
    		Protective gloves. Protective clothing.
    		Remove contaminated clothes. Rinse skin with plenty of water or shower.
  • EYES
    		• Redness.
    		Safety goggles or eye protection in combination with breathing protection.
    		First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then take to a doctor.
  • INGESTION

    		• Do not eat, drink, or smoke during work.
    		Rinse mouth.
    SPILLAGE DISPOSAL STORAGE PACKAGING & LABELLING
    Evacuate danger area! Collect leaking and spilled liquid in sealable containers as far as possible. Absorb remaining liquid in sand or inert absorbent and remove to safe place. Carefully collect remainder (extra personal protection: self-contained breathing apparatus).
    		Fireproof. Separated from reducing agents, alkali metals, strong oxidants.
    		Airtight. Unbreakable packaging; put breakable packaging into closed unbreakable container.
    UN Hazard Class: 3
    UN Packing Group: III
    SEE IMPORTANT INFORMATION ON BACK
    ICSC: 0032 Prepared in the context of cooperation between the International Programme on Chemical Safety & the Commission of the European Communities © IPCS CEC 1993 No modifications to the International version have been made except to add the OSHA PELs, NIOSH RELs and IDLH values.

    International Chemical Safety Cards

    CYCLOHEXANETHIOL ICSC: 0032

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    PHYSICAL STATE; APPEARANCE:
     LIQUID , WITH CHARACTERISTIC ODOUR.

    PHYSICAL DANGERS:

    CHEMICAL DANGERS:
     The substance decomposes on burning producing highly toxic gases including sulfur dioxide (see ICSC # 0074). Reacts with strong oxidants, reducing agents, and alkali metals.

    OCCUPATIONAL EXPOSURE LIMITS (OELs):
     TLV not established.
    MAK not established.
    OSHA PEL: none
    NIOSH REL: C 0.5 ppm (2.4 mg/m3) 15-minute
    NIOSH IDLH: No data


    		ROUTES OF EXPOSURE:
     The substance can be absorbed into the body by inhalation, through the skin, and by ingestion.

    INHALATION RISK:
     A harmful contamination of the air can be reached very quickly on evaporation of this substance at 20°C.

    EFFECTS OF SHORT-TERM EXPOSURE:
     The substance irritates the eyes, the skin, and the respiratory tract. The substance may cause effects on the central nervous system , resulting in respiratory failure.

    EFFECTS OF LONG-TERM OR REPEATED EXPOSURE:
     Repeated or prolonged contact with skin may cause dermatitis.
    PHYSICAL
    PROPERTIES
    Boiling point: 158°C
    Melting point: -118°C
    Relative density (water = 1): 0.98
    Solubility in water: none
    Vapour pressure, kPa at 20°C: 1.3
    		 Relative vapour density (air = 1): 4.0
    Relative density of the vapour/air-mixture at 20°C (air = 1): 1.04
    Flash point: 43°C c.c.
    Auto-ignition temperature: see Notes°C
    Explosive limits, vol% in air: see Notes
    ENVIRONMENTAL
    DATA
    N O T E S
    Auto-ignition temperature is unknown in literature. Explosive limits are unknown in literature, although the substance is combustible and has a flash point 55°C.
    Transport Emergency Card: TEC (R)-30G36
    NFPA Code: H; F 2; R 0;
    ADDITIONAL INFORMATION


    ICSC: 0032 CYCLOHEXANETHIOL
    © IPCS, CEC, 1993
    IMPORTANT LEGAL NOTICE: Neither NIOSH, the CEC or the IPCS nor any person acting on behalf of NIOSH, the CEC or the IPCS is responsible for the use which might be made of this information. This card contains the collective views of the IPCS Peer Review Committee and may not reflect in all cases all the detailed requirements included in national legislation on the subject. The user should verify compliance of the cards with the relevant legislation in the country of use. The only modifications made to produce the U.S. version is inclusion of the OSHA PELs, NIOSH RELs and IDLH values.