International Chemical Safety Cards
ENDOSULFAN (MIXED ISOMERS)
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ICSC: 0742
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ENDOSULFAN (MIXED ISOMERS)
(1,4,5,6,7,7-Hexachloro-8,9,10-trinorborn-5-en-2,3-ylenebismethylene)sulfite
6,9-Methano-2,4,3-benzodioxathiepin, 6,7,8,9,10,10-hexachloro-1,5,5a,6,9,9a-hexahydro-, 3-oxide
C9H6Cl6O3S
Molecular mass: 406.9
CAS # 115-29-7
RTECS # RB9275000
ICSC # 0742
UN # 2761
EC # 602-052-00-5
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TYPES OF HAZARD/ EXPOSURE
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ACUTE HAZARDS/ SYMPTOMS
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PREVENTION
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FIRST AID/ FIRE FIGHTING
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FIRE
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Not combustible.
Liquid formulations containing organic solvents may be flammable.
Gives off irritating or toxic fumes (or gases) in a fire.
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In case of fire in the surroundings: all extinguishing agents allowed.
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EXPLOSION
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In case of fire: keep drums, etc., cool by spraying with water.
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EXPOSURE
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PREVENT DISPERSION OF DUST!
STRICT HYGIENE!
AVOID EXPOSURE OF ADOLESCENTS AND CHILDREN!
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IN ALL CASES CONSULT A DOCTOR!
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INHALATION
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(see Ingestion).
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Local exhaust or breathing protection.
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Fresh air, rest.
Refer for medical attention.
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SKIN
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MAY BE ABSORBED!
(See Ingestion).
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Protective gloves.
Protective clothing.
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Remove contaminated clothes.
Rinse and then wash skin with water and soap.
Refer for medical attention.
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EYES
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Face shield,
or eye protection in combination with breathing protection.
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First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then take to a doctor.
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INGESTION
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Blue lips or fingernails.
Confusion.
Convulsions.
Diarrhoea.
Dizziness.
Headache.
Laboured breathing.
Nausea.
Unconsciousness.
Vomiting.
Weakness.
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Do not eat, drink, or smoke during work.
Wash hands before eating.
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Induce vomiting (ONLY IN CONSCIOUS PERSONS!).
Rest.
Refer for medical attention.
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SPILLAGE DISPOSAL
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STORAGE
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PACKAGING & LABELLING
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Do NOT wash away into sewer.
Sweep spilled substance into sealable containers; if appropriate, moisten first to prevent dusting.
Carefully collect remainder,
then remove to safe place.
(extra personal protection: chemical protection suit including self-contained breathing apparatus).
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Provision to contain effluent from fire extinguishing.
Separated from
acids,
bases, iron, food and feedstuffs.
Dry.
Well closed.
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Do not transport with food and feedstuffs.
T symbol
N symbol
R: 24/25-36-50/53
S: (1/2-)28-36/37-45-60-61
UN Hazard Class: 6.1
UN Packing Group: II
Severe marine pollutant.
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SEE IMPORTANT INFORMATION ON BACK
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ICSC: 0742
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Prepared in the context of cooperation between the International Programme on Chemical Safety & the Commission of the European Communities © IPCS CEC 1993
No modifications to the International version have been made except to add the OSHA PELs, NIOSH RELs and IDLH values.
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