International Chemical Safety Cards FONOFOS ICSC: 0708 FONOFOS O-Ethyl S-phenylethylphosphonodithioate C5H5SPSCH2CH3OCH2CH3 / C10H15OPS2 Molecular mass: 246.3 CAS # 944-22-9 RTECS # TA5950000 ICSC # 0708 UN # 3018 EC # 015-091-00-2 TYPES OF HAZARD/ EXPOSURE ACUTE HAZARDS/ SYMPTOMS PREVENTION FIRST AID/ FIRE FIGHTING FIRE Combustible. Liquid formulations containing organic solvents may be flammable. Gives off irritating or toxic fumes (or gases) in a fire. Foam, powder, carbon dioxide. EXPLOSION EXPOSURE PREVENT GENERATION OF MISTS! STRICT HYGIENE! AVOID EXPOSURE OF ADOLESCENTS AND CHILDREN! IN ALL CASES CONSULT A DOCTOR! INHALATION Pupillary constriction, muscle cramp, excessive salivation. Sweating. Nausea. Dizziness. Laboured breathing. Convulsions. Unconsciousness. Ventilation, local exhaust, or breathing protection. Fresh air, rest. Refer for medical attention. SKIN MAY BE ABSORBED! (further see Inhalation). Protective gloves. Protective clothing. Remove contaminated clothes. Rinse and then wash skin with water and soap. Refer for medical attention. EYES Liquid or aerosol may be absorbed. Redness. Pain. Blurred vision. Face shield, or eye protection in combination with breathing protection. First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then take to a doctor. INGESTION Weakness. Abdominal cramps. Vomiting. Diarrhoea (further see Inhalation). Do not eat, drink, or smoke during work. Wash hands before eating. Induce vomiting (ONLY IN CONSCIOUS PERSONS!). Rest. Refer for medical attention. SPILLAGE DISPOSAL STORAGE PACKAGING & LABELLING Collect leaking and spilled liquid in sealable containers as far as possible. Absorb remaining liquid in sand or inert absorbent and remove to safe place. Do NOT wash away into sewer (extra personal protection: complete protective clothing including self-contained breathing apparatus). Separated from food and feedstuffs. Keep in a well-ventilated room. Do not transport with food and feedstuffs. T+ symbol N symbol R: 27/28-50/53 S: (1/2)28-36/37-45-60-61 UN Hazard Class: 6.1 UN Packing Group: I Severe marine pollutant. SEE IMPORTANT INFORMATION ON BACK ICSC: 0708 Prepared in the context of cooperation between the International Programme on Chemical Safety & the Commission of the European Communities © IPCS CEC 1993 No modifications to the International version have been made except to add the OSHA PELs, NIOSH RELs and IDLH values.

International Chemical Safety Cards FONOFOS ICSC: 0708 I M P O R T A N T D A T A PHYSICAL STATE; APPEARANCE: CLEAR COLOURLESS LIQUID , WITH CHARACTERISTIC ODOUR. PHYSICAL DANGERS: CHEMICAL DANGERS: Substance is hydrolyzed in contact with strong acids and alkalis. OCCUPATIONAL EXPOSURE LIMITS (OELs): TLV: ppm; 0.1 mg/m3 (as TWA) (skin) (ACGIH 1996). OSHA PEL: none NIOSH REL: TWA 0.1 mg/m3 skin NIOSH IDLH: No data ROUTES OF EXPOSURE: The substance can be absorbed into the body by inhalation, through the skin, the eyes and by ingestion. INHALATION RISK: Evaporation at 20°C is negligible; a harmful concentration of airborne particles can, however, be reached quickly on spraying. EFFECTS OF SHORT-TERM EXPOSURE: Cholinesterase inhibitor. Exposure above the OEL may result in death. The effects may be delayed. Medical observation is indicated. EFFECTS OF LONG-TERM OR REPEATED EXPOSURE: Cholinesterase inhibitor; cumulative effect is possible: see acute hazards/symptoms. PHYSICAL PROPERTIES Boiling point at 0.013 kPa: 130°C Melting point: 30°C Relative density (water = 1): 1.16 Solubility in water: none Vapour pressure, Pa at 25°C: 0.03 Flash point: 94°C c.c. Octanol/water partition coefficient as log Pow: 3.94 ENVIRONMENTAL DATA This substance may be hazardous to the environment; special attention should be given to honey bees and water organisms. Avoid release to the environment in circumstances different to normal use. N O T E S Depending on the degree of exposure, periodic medical examination is indicated. The symptoms of acute intoxication do not become manifest until some hours have passed. Specific treatment is necessary in case of poisoning with this substance; the appropriate means with instructions must be available. Carrier solvents used in commercial formulations may change physical and toxicological properties. Do NOT take working clothes home. Difonate, Dyfonate 2G, and Stauffer N 2790 are trade names. Transport Emergency Card: TEC (R)-61G44 ADDITIONAL INFORMATION ICSC: 0708 FONOFOS © IPCS, CEC, 1993

IMPORTANT LEGAL NOTICE: Neither NIOSH, the CEC or the IPCS nor any person acting on behalf of NIOSH, the CEC or the IPCS is responsible for the use which might be made of this information. This card contains the collective views of the IPCS Peer Review Committee and may not reflect in all cases all the detailed requirements included in national legislation on the subject. The user should verify compliance of the cards with the relevant legislation in the country of use. The only modifications made to produce the U.S. version is inclusion of the OSHA PELs, NIOSH RELs and IDLH values.