International Chemical Safety Cards

DICHLOROMONOFLUOROMETHANE ICSC: 1106

DICHLOROMONOFLUOROMETHANE
Fluorodichloromethane
Fluorocarbon 21
Refrigerant 21
(cylinder)
CHCl2F
Molecular mass: 102.9
CAS # 75-43-4
RTECS # PA8400000
ICSC # 1106
UN # 1029
TYPES OF
HAZARD/
EXPOSURE 		ACUTE HAZARDS/
SYMPTOMS 		PREVENTION FIRST AID/
FIRE FIGHTING
FIRE Not combustible. Gives off irritating or toxic fumes (or gases) in a fire.

In case of fire in the surroundings: all extinguishing agents allowed.
EXPLOSION

In case of fire: keep cylinder cool by spraying with water.
EXPOSURE
STRICT HYGIENE!

  • INHALATION
    		• Drowsiness. Unconsciousness.
    		Ventilation, local exhaust, or breathing protection.
    		Fresh air, rest. Artificial respiration if indicated. Refer for medical attention.
  • SKIN
    		• ON CONTACT WITH LIQUID: FROSTBITE.
    		Cold-insulating gloves. Protective clothing.
    		ON FROSTBITE: rinse with plenty of water, do NOT remove clothes. Refer for medical attention.
  • EYES

    		• Safety goggles or eye protection in combination with breathing protection.
    		First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then take to a doctor.
  • INGESTION

    		• Do not eat, drink, or smoke during work.

    SPILLAGE DISPOSAL STORAGE PACKAGING & LABELLING
    Ventilation. NEVER direct water jet on liquid. Do NOT let this chemical enter the environment (extra personal protection: self-contained breathing apparatus).
    		Fireproof if in building. Separated from strong acids, chemically active metals. Cool. Keep in a well-ventilated room.

    UN Hazard Class: 2.2
    SEE IMPORTANT INFORMATION ON BACK
    ICSC: 1106 Prepared in the context of cooperation between the International Programme on Chemical Safety & the Commission of the European Communities © IPCS CEC 1993 No modifications to the International version have been made except to add the OSHA PELs, NIOSH RELs and IDLH values.

    International Chemical Safety Cards

    DICHLOROMONOFLUOROMETHANE ICSC: 1106

    I
    M
    P
    O
    R
    T
    A
    N
    T

    D
    A
    T
    A
    PHYSICAL STATE; APPEARANCE:
     CLEAR, COLOURLESS GAS OR COMPRESSED LIQUEFIED GAS , WITH CHARACTERISTIC ODOUR.

    PHYSICAL DANGERS:
     The gas is heavier than air.

    CHEMICAL DANGERS:
     The substance decomposes on heating producing corrosive and highly toxic fumes (hydrogen chloride - see ICSC # 0163, hydrogen fluoride - see ICSC # 0283, and phosgene - see ICSC # 0007). Reacts violently with chemically active metals. Reacts with acids or acid fumes producing highly toxic fumes (chlorine, fluorine). Attacks some forms of plastics, rubber and coatings.

    OCCUPATIONAL EXPOSURE LIMITS (OELs):
     TLV: 10 ppm; 42 mg/m3 as TWA (ACGIH 1991-1992).
    OSHA PEL: TWA 1000 ppm (4200 mg/m3)
    NIOSH REL: TWA 10 ppm (40 mg/m3)
    NIOSH IDLH: 5000 ppm


    		ROUTES OF EXPOSURE:
     The substance can be absorbed into the body by inhalation.

    INHALATION RISK:
     A harmful concentration of this gas in the air will be reached very quickly on loss of containment.

    EFFECTS OF SHORT-TERM EXPOSURE:
     The liquid may cause frostbite. The substance may cause effects on the central nervous system at high concentrations. Exposure far above OEL could cause the heart to beat irregularly.

    EFFECTS OF LONG-TERM OR REPEATED EXPOSURE:
    PHYSICAL
    PROPERTIES
    Boiling point: 8.9°C
    Melting point: -135°C
    Solubility in water: poor (1 g/100 ml at 20°C)
    Vapour pressure, kPa at 20°C: 160
    		 Relative vapour density (air = 1): 3.8
    Auto-ignition temperature: 522°C
    Octanol/water partition coefficient as log Pow: 1.55
    ENVIRONMENTAL
    DATA
         		This substance may be hazardous to the environment; special attention should be given to ozone layer.
    NOTES
    Specific treatment is necessary in case of poisoning with this substance; the appropriate means with instructions must be available. High concentrations in the air cause a deficiency of oxygen with the risk of unconsciousness or death. Check oxygen content before entering area. Do NOT use in the vicinity of a fire or a hot surface, or during welding. Turn leaking cylinder with the leak up to prevent escape of gas in liquid state. Freon 21, Genetron 21, Arcton 7 and Algofrene type 5 are trade names.
    ADDITIONAL INFORMATION


    ICSC: 1106 DICHLOROMONOFLUOROMETHANE
    © IPCS, CEC, 1993
    IMPORTANT LEGAL NOTICE: Neither NIOSH, the CEC or the IPCS nor any person acting on behalf of NIOSH, the CEC or the IPCS is responsible for the use which might be made of this information. This card contains the collective views of the IPCS Peer Review Committee and may not reflect in all cases all the detailed requirements included in national legislation on the subject. The user should verify compliance of the cards with the relevant legislation in the country of use. The only modifications made to produce the U.S. version is inclusion of the OSHA PELs, NIOSH RELs and IDLH values.