International Chemical Safety Cards

2-METHOXYETHANOL ICSC: 0061

2-METHOXYETHANOL
Ethylene glycol monomethyl ether
Monomethyl glycol ether
CH3OCH2CH2OH
Molecular mass: 76.1
CAS # 109-86-4
RTECS # KL5775000
ICSC # 0061
UN # 1188
EC # 603-011-00-4
TYPES OF
HAZARD/
EXPOSURE 		ACUTE HAZARDS/
SYMPTOMS 		PREVENTION FIRST AID/
FIRE FIGHTING
FIRE Flammable.
NO open flames, NO sparks, and NO smoking. NO contact with strong oxidants.
Powder, alcohol-resistant foam, water spray, carbon dioxide.
EXPLOSION Above 39°C explosive vapour/air mixtures may be formed.
Above 39°C use a closed system, ventilation, and explosion-proof electrical equipment.
In case of fire: keep drums, etc., cool by spraying with water.
EXPOSURE
AVOID EXPOSURE OF (PREGNANT) WOMEN!
IN ALL CASES CONSULT A DOCTOR!
  • INHALATION
    		• Confusion. Dizziness. Headache. Nausea. Unconsciousness. Vomiting. Weakness.
    		Ventilation, local exhaust, or breathing protection.
    		Fresh air, rest. Artificial respiration if indicated. Refer for medical attention.
  • SKIN
    		• MAY BE ABSORBED! (Further see Inhalation).
    		Protective gloves. Protective clothing.
    		Remove contaminated clothes. Rinse skin with plenty of water or shower. Refer for medical attention.
  • EYES
    		• Blurred vision.
    		Safety goggles or face shield.
    		First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then take to a doctor.
  • INGESTION
    		• (further see Inhalation).
    		Do not eat, drink, or smoke during work.
    		Rinse mouth. Induce vomiting (ONLY IN CONSCIOUS PERSONS!). Refer for medical attention.
    SPILLAGE DISPOSAL STORAGE PACKAGING & LABELLING
    Collect leaking and spilled liquid in sealable containers as far as possible. Wash away remainder with plenty of water (extra personal protection: self-contained breathing apparatus).
    		Fireproof. Separated from strong oxidants. Keep in the dark.
    		Airtight.
    T symbol
    R: 60-61-10-20/21/22
    S: 53-45
    UN Hazard Class: 3
    UN Packing Group: III
    SEE IMPORTANT INFORMATION ON BACK
    ICSC: 0061 Prepared in the context of cooperation between the International Programme on Chemical Safety & the Commission of the European Communities © IPCS CEC 1993 No modifications to the International version have been made except to add the OSHA PELs, NIOSH RELs and IDLH values.

    International Chemical Safety Cards

    2-METHOXYETHANOL ICSC: 0061

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    PHYSICAL STATE; APPEARANCE:
     COLOURLESS LIQUID , WITH CHARACTERISTIC ODOUR.

    PHYSICAL DANGERS:

    CHEMICAL DANGERS:
     The substance can form explosive peroxides. The substance decomposes on burning and on contact with strong caustics, producing toxic gas. Reacts with strong oxidants causing fire and explosion hazard.

    OCCUPATIONAL EXPOSURE LIMITS (OELs):
     TLV: 5 ppm; 16 mg/m3 (as TWA) (skin) (ACGIH 1992-1993).
    MAK: 5 ppm; 15 mg/m3; II,1; H; B (1993).
    OSHA PEL: TWA 25 ppm (80 mg/m3) skin
    NIOSH REL: TWA 0.1 ppm (0.3 mg/m3) skin
    NIOSH IDLH: 200 ppm


    		ROUTES OF EXPOSURE:
     The substance can be absorbed into the body by inhalation, through the skin, and by ingestion.

    INHALATION RISK:
     A harmful contamination of the air can be reached rather quickly on evaporation of this substance at 20°C.

    EFFECTS OF SHORT-TERM EXPOSURE:
     The substance irritates the eyes and the respiratory tract. The substance may cause effects on the central nervous system, liver, and kidneys. Exposure could cause lowering of consciousness. Medical observation is indicated.

    EFFECTS OF LONG-TERM OR REPEATED EXPOSURE:
     The liquid defats the skin. The substance may have effects on the blood , resulting in anaemia and lesions of blood cells. May cause reproductive toxicity in humans.
    PHYSICAL
    PROPERTIES
    Boiling point: 125°C
    Melting point: -85°C
    Relative density (water = 1): 0.96
    Solubility in water: miscible
    Vapour pressure, kPa at 20°C: 0.83
    Relative vapour density (air = 1): 2.6
    		 Relative density of the vapour/air-mixture at 20°C (air = 1): 1.01
    Flash point: 39°C c.c.
    Auto-ignition temperature: 285°C
    Explosive limits, vol% in air: 1.8-14
    Octanol/water partition coefficient as log Pow: -0.503
    ENVIRONMENTAL
    DATA
         		This substance may be hazardous to the environment; special attention should be given to water organisms.
    N O T E S
    Depending on the degree of exposure, periodic medical examination is indicated. The odour warning when the exposure limit value is exceeded is insufficient. Check for peroxides prior to distillation; eliminate if found. Keep in dark because of the possible formation of explosive peroxides.
    Transport Emergency Card: TEC (R)-30G35
    NFPA Code: H 2; F 2; R 0;
    ADDITIONAL INFORMATION


    ICSC: 0061 2-METHOXYETHANOL
    © IPCS, CEC, 1993
    IMPORTANT LEGAL NOTICE: Neither NIOSH, the CEC or the IPCS nor any person acting on behalf of NIOSH, the CEC or the IPCS is responsible for the use which might be made of this information. This card contains the collective views of the IPCS Peer Review Committee and may not reflect in all cases all the detailed requirements included in national legislation on the subject. The user should verify compliance of the cards with the relevant legislation in the country of use. The only modifications made to produce the U.S. version is inclusion of the OSHA PELs, NIOSH RELs and IDLH values.